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迫田直也助教ら I2CNER附属次世代冷媒物性評価研究センター(NEXT-RP)研究グループによる論文が『Journal of Chemical & Engineering Data』に掲載されました

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I2CNER熱科学研究部門及び附属次世代冷媒物性評価研究センター(NEXT-RP)所属の迫田直也助教、河野正道教授、小山繁教授、東之弘教授、髙田保之教授らによる研究論文が、アメリカ化学会発行の学術誌『Journal of Chemical & Engineering Data』に掲載されました。

 

論文:Gaseous PVT Property Measurements of cis-1,3,3,3-Tetrafluoropropene

著者:Naoya Sakoda, Jiang Shiheng, Masamichi Kohno, Shigeru Koyama, Yukihiro Higashi, and Yasuyuki Takata

DOI:10.1021/acs.jced.7b00263

 

■ Abstract

PVT properties in the vapor phase of cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) were measured by a multiple expansion method in the temperature range from 353 to 413 K and at pressures up to 2.7 MPa. Thirty data along four isotherms are obtained in the temperatures between 353 and 413 K. The vapor pressures at the temperatures were also measured by adding a sample of R1234ze(Z) to a sample cell at the vapor–liquid equilibrium conditions. The uncertainties in temperature and pressure measurements are estimated to be within 6 mK and 0.3 kPa, respectively. The expanded uncertainty in density measurement is estimated within no greater than 0.12% (k = 2). The obtained PVT properties and vapor pressures are compared with the existing equation of state.