I²CNER Research Seeds

  • Electrical Conversion
  • Hydrogen Energy

Energy conversion, Hydrogen production, Processing and upscaling, Triple conducting electrode

Kwati, Leonard

Associate Professor

Research Outline

Development and upscaling of highly efficient solid oxide protonic cells (PCEC/PCFCs).
  • Process highly efficient protonic fuel and electrolysis cells using newly tailored electrolytes and electrode materials. Micro and nano-structural analysis of the half-cell interfaces.
  • Upscaling and Increasing understanding of PCEC/PCFCs and stack degradation.
  • Improving energy efficiency over various operating conditions and reversible operation.
Development/engineering of proton transport in air electrodes
  • Design-compatible, durable, and efficient triple-conducting air electrode materials explicitly tailored for protonic electrolytes.
  • Understanding the fundamental properties that make excellent triple-conducting electrodes and the underlying defect interactions and mechanisms that dictate their operation dynamics.

Research Methods and Facilities

PCEC/PCFCs half-cell processing by inverse tape casting.

The protocol consists of casting thin layers onto a silicone-coated polymeric foil and drying at room temperature. This approach enables the formation of defect-free layers and Flat planar half-cells with impressive dimensions of up to 100 mm × 100 mm × 0.5 mm.   We use NiO-SrZr0.5Ce0.4Y0.1O3-δ as the substrate, which ensures minimal warping and no cracks in the end-fired state. The electrolytes in our half-cell are appropriately dense and gas-tight after co-firing at 1300 ℃, which is about 200 ℃ lower than required for the electrolyte alone.

Assessment of fast ionic kinetics by advanced techniques.

We use an innovative approach to evaluate proton kinetic properties in perovskite-type oxides via a combination of isotope exchange experiments (18O2 and 2H2O tracers) and TOF-SIMS depth profiling. Based on a deeper understanding of the reaction mechanisms and their potential to reduce PCFC/ PCFC costs, we will establish a design concept for high-performing protonic air electrodes.